Keith B. Oldham - Recent Articles
Recent Articles (since 1996)
(215) "The charging, by a potential step, of
the double layer at the surface of an inlaid-disk electrode", Jan C.
Myland and Keith B. Oldham, Journal of Electroanalytical Chemistry, in
preparation (2004).
(214) "Modelling electrochemistry at
disk electrodes through oblate spheroidal coordinates ", Jan C. Myland and
Keith B. Oldham, Journal of Electroanalytical Chemistry, submitted (2004).
(213) "Cottrell’s equation
revisited: An intuitive but unreliable, novel approach to the tracking of
electrochemical diffusion ", Jan C. Myland and Keith B. Oldham,
Electrochemistry Communications, in press (2004).
(212) "Electrode ‘edge
effects’ analyzed by the Green method", Keith B. Oldham, Journal of
Electroanalytical Chemistry, submitted (2003).
(211) "The RC time ‘constant’ at a disk electrode", Keith B.
Oldham, Electrochemistry Communications, 6, 210-214 (2004).
(210) "Solution to the diffusion
equation for triangles", Jan C. Myland and Keith B. Oldham, SIAM Journal
of Applied Mathematics, submitted (2004).
(209) "Constant-current unsupported
electrolysis in a thin cell: a comparative study of analytical and simulative
modelling", Jan C. Myland and Keith B. Oldham, Journal of
Electroanalytical Chemistry, in press (2004).
(208) "A Green
function for the equilateral triangle", Michelle E. Johnston, Jan C.
Myland and Keith B. Oldham, Zeitschrift für angewandte Mathematik und Physik,
submitted (2003).
(207) "Facile analysis of EC cyclic
voltammograms", Conor Hogan, Alan M. Bond, Jan C. Myland and Keith B.
Oldham, Analytical Chemistry, in press (2003).
(206) "Convolutive modeling of the disk
electrode geometry under reversible conditions", Peter J. Mahon and Keith
B. Oldham, Journal of Electroanalytical Chemistry, in preparation (2004).
(205) "A The transient current at the
disk electrode under diffusion control: a new determination by the Cope-Tallman
method", Peter J. Mahon and Keith B. Oldham, Journal of Electroanalytical
Chemistry, in preparation (2004).
(204) "A general analytical treatment of
modulated linear-scan voltammetry for reversible processes", Jan C. Myland
and Keith B. Oldham, Journal of Electroanalytical Chemistry, 535, 27-35
(2002).
(203) "Identifying power series through
hypergeometric functions", Keith B. Oldham, (unpublished 2002).
(202) "Convolutive modelling in the
absence of supporting electrolyte: coping with migration and changing
resistance in predicting voltammetry", Jan C. Myland and Keith B. Oldham,
Journal of Electroanalytical chemistry, 529, 66-74 (2002).
(201) "Overcoming electroneutrality:
Concentrative and electrical conditions inside a charged droplet of electrolyte
solution", Jan C. Myland and Keith B. Oldham, Journal of Electroanalytical
Chemistry, 522, 115-123 (2002).
(200) "Electrochemical study of large
channels in porous rocks", Sten O. Engblom, Jan C. Myland, Keith B.
Oldham, Alicia L. Taylor and Wendy C. Topic, Journal of Applied
Electrochemistry, 33, 51-59 (2003).
(199) "The effect of periodic modulation
on the aperiodic current in linear-scan and cyclic voltammetries", David
J. Gavaghan, Jan C. Myland and Keith B. Oldham, Journal of Electroanalytical
Chemistry,516, 2-9 (2001).
(198) "A full analytic treatment of
reversible linear-scan voltammetry with square-wave modulation", Keith B.
Oldham, David J. Gavaghan and Alan M. Bond, Journal of Physical Chemistry B, 160,
152-157 (2002).
(197) "A model of ionic current
densities in the vicinity of a corroding disk-shaped region", Dee
Livingstone-Bridge, Jan C. Myland and Keith B. Oldham, Electrochemistry
Communications, 3, 384-389 (2001).
(196) "A model of voltammetry in a thin
organic layer sandwiched between an electrode and an aqueous solution.
Convolutive modelling in the absence of supporting electrolyte”, Jan C.
Myland and Keith B. Oldham, Journal of Electroanalytical Chemistry, 530,
1-9 (2002).
(195) "Corrosion current densities at a
disk-shaped inclusion", L.C. Roland Alfred, Jan C. Myland and Keith B.
Oldham, Journal of Solid State Electrochemistry, 6, 172-182 (2002).
(194) "Polarization inventory
diagrams", Jan C. Myland and Keith B. Oldham, Journal of Electroanalytical
Chemistry, 504, 137-145 (2001).
(193) "Large amplitude a.c. voltammetry
- a comparison between theory and experiment", Sten O. Engblom, Jan C.
Myland, Keith B. Oldham and Alicia L. Taylor, Electroanalysis, 13,
626-630 (2001)
(192) "A fresh approach to Voltammetric
modelling”, Peter J. Mahon, Jan C. Myland and Keith B. Oldham, Journal of
Electroanalytical Chemistry, 537, 1-5 (2002).
(191) "Uncompensated resistance; Part I:
the effect of cell geometry", Jan C. Myland and Keith B. Oldham,
Analytical Chemistry, 72, 3972-3980 (2000).
(190) "Steady-state voltammetry at a
rotating disk electrode in the absence of supporting electrolyte ", Keith
B. Oldham, Journal of Physical Chemistry B, 104, 4703-4706 (2000).
(189) "Which of three
voltammetric methods, when applied to a reversible electrode reaction, can best
cope with double-layer capacitance and severe uncompensated resistance?",
Jan C. Myland and Keith B. Oldham, Analytical Chemistry, 72, 3210-3217
(2000).
(188) "Modelling
reversible cyclic voltammetry at the one-dimensional junction established by
three-phases: an organic liquid containing a neutral electroactive solute, an
aqueous electrolyte solution, and an electronic conductor" Jan C. Myland
and Keith B. Oldham, Electrochemistry Communications, 2, 541-546 (2000).
(187) "Uncompensated resistance; Part
II: the effect of reference electrode nonideality", Keith B. Oldham and
Nicholas P.C. Stevens, Analytical Chemistry, 72, 541-546 (2000).
(186) "How is the theory of steady-state
voltammetry affected when the electroneutrality approximation is
discarded?" Keith B. Oldham, 508, 28-40 (2001)
(185) "Analysis of a simplified form of
square wave voltammetry in the frequency domain". David J. Gavaghon, Darryl
Elton, Keith B. Oldham and Alan M. Bond, Analytical Chemistry, in press (2001).
(184) "Experimental evaluation of cyclic
voltammetry of highly charged species at macrodisk electrodes without added
supporting electrolyte. Influence of enhanced convective mass transport
in a study of the [S2Mo18O62]4 /5 /6 reduction processes in
acetonitrile", Alan M. Bond, Darren C. Coomber, Stephen W. Feldberg, Keith
B. Oldham, Truc Vu, Analytical Chemistry, 73, 352-359 (2001).
(183) "Modelling of solid-state voltammetry
of immobilized microcrystals assuming an initiation of the electrochemical
reaction at a three-phase junction", Uwe Schröder, Keith B. Oldham, Jan C.
Myland Peter J. Mahon and Fritz Scholz, Journal of Solid State
Electrochemistry, 4, 314-324 (2000).
(182) "Steady-state limiting currents in
a Nernst layer in the absence of supporting electrolyte", in preparation.
(181) "Use of semiintegration to measure
uncompensated resistance in cyclic voltammetry", Alan M. Bond, Keith B.
Oldham and Graeme Snook, Analytical Chemistry, 72, 3492-6496 (2000).
(180) "Limiting currents in
potentiostatic voltammetry without supporting electrolyte", Jan C. Myland
and Keith B. Oldham, Electrochemistry Communications, 1, 467-471 (1999).
(179) "Must a.c. voltammetry employ
small signals?", Sten O. Engblom, Jan C. Myland and Keith B. Oldham,
Journal of Electroanalytical Chemistry, 480, 120-132 (2000).
(178) "The principle of unchanging total
concentration and its implications for modeling unsupported transient
voltammetry", Keith B. Oldham and Stephen W. Feldberg, Journal of Physical
Chemistry B, 103, 1699-1704 (1999).
(177) "Convolutive modelling: A
third route to predict voltammograms", Peter J. Mahon and Keith B. Oldham,
Proceedings of the 195th Conference of the Electrochemical Society (1999).
(176) "Concentrations of electroactive
solutes, during cyclic and other voltammetries, at points away from the
electrode surface; Part II: three applications", Jan C. Myland and Keith
B. Oldham, Analytical Chemistry, unpublished.
(175) "Incorporating electrode kinetics
into the convoluted modelling of reactions at planar, cylindrical and spherical
electrodes", Peter J. Mahon and Keith B. Oldham, Journal of
Electroanalytical Chemistry, 46, 953-965 (2001).
(174) "Concentrations of electroactive
solutes, during cyclic and other voltammetries, at points away from the
electrode surface; Part I: fundamental relationships and their
validation", Jan C. Myland and Keith B. Oldham, Analytical Chemistry, 71,
183-195 (1999).
(173) "Steady-state and solution-phase
reactions at the interface between an electrode and a supporting electrolyte
solution in dichloromethane when microcrystals of the fullerene C60 adhere to
the electrode", Alan M. Bond, Stephen W. Feldberg, Wujian Miao, Keith B.
Oldham and Colin L. Raston, 501, 22-32 (2001).
(172) "Convolutive modelling of
electrochemical processes based on the relationship between the current and the
surface concentration ", Peter J. Mahon and Keith B. Oldham, Journal of
Electroanalytical Chemistry, 464, 1-13 (1999).
(171) "Electrochemical study of the pore
structure of sandstone and similar media", Jan C. Myland, Keith B. Oldham,
Jörg Schiewe and Alicia L. Taylor, Canadian Journal of Chemistry, 76,
1688-1694 (1998).
(170) "An introduction to the fractional
calculus and some applications", Keith B. Oldham, Proceedings of the 1996
Conference on Transform Methods and Special Functions, Varna, Bulgaria, 598-610
(1998).
(169) "Theory of potential relaxation
after interrupting a steady-state current", Keith B. Oldham and Jan C.
Myland, Canadian Journal of Chemistry, 75, 1523-1528 (1997).
(168) "A study of the interaction
between silver and other heavy metal ions and the ionophore, S,S-dipropyl
pyridine-2,6-dicarbothioate", Robert W. Cattrall, C. Grace Gregorio,
Richard D. Webster, Alan M. Bond and Keith B. Oldham, Analytical Chemistry, 69,
3353-3359 (1997).
(167) "Voltammetric modelling via
extended semiintegrals", Peter J. Mahon and Keith B. Oldham, Journal of
Electroanalytical Chemistry, 445, 179-195 (1998).
(166) "Voltammetry at a three-phase
junction", Keith B. Oldham, Journal of Solid State Electrochemistry, 2,
367-377 (1998).
(165) "Limiting currents for
steady-state electrolysis of an equilibrium mixture, with and without
supporting inert electrolyte", Keith B. Oldham, Analytical Chemistry, 69,
446 (1997).
(164) "Steady-state electrolysis at a
grooved or ridged plane", Keith B. Oldham, Journal of Solid State
Electrochemistry, 1, 36-44 (1997).
(163) "Electrochemical Characterization of
Porous Media", Muthoni G. Kamau, Jan C. Myland, and Keith B. Oldham,
Proceedings of the International Conference on Porous Media and Their
Applications in Science, Engineering and Industry, 433-440 (1996).
(162) "Effect of ion pairing on
steady-state voltammetric limiting currents at microelectrodes. Part II:
experimental studies on charged (Br , Ag+) and uncharged (copper
diethyldithiocarbamate) species in toluene", J.H. Santos, T.J. Cardwell,
A.M. Bond and Keith B. Oldham, Journal of Electroanalytical Chemistry, 430,
39-44 (1997).
(161) "Voltammetric effects of
microelectrode geometry", Keith B. Oldham, in "New Directions in
electroanalytical chemistry" (eds: J. Leddy and R.M. Wightman) Proceedings
of the 189th Conference of the Electrochemical Society, 96-9,12-25 (1996).
(160) "Effect of diffusion coefficient
diversity on steady-state voltammetry when homogeneous equilibria and migration
are encountered", Keith B. Oldham, Analytical Chemistry, 68,
4173-4179 (1996).
(159) "Linear-scan anodic stripping
voltammetry with thin-film electrodes: Theory of the stripping stage and
experimental tests", Jorg Schiewe, Keith B. Oldham, Jan C. Myland, Alan M.
Bond, Victoria Vicente-Beckett and Stephen Fletcher, Analytical Chemistry, 69,
2673- 2681 (1997).
(158) "Effect of ion pairing on
steady-state voltammetric limiting currents at microelectrodes. Part I:
theoretical principles", Keith B. Oldham, Terence J. Cardwell, Jose H.
Santos and Alan M. Bond, Journal of Electroanalytical Chemistry, 430,
35-37 (1997).
(157) "The shape of linear-scan
voltammograms for totally irreversible reactions at planar electrodes",
Davis C. Cope, Jan C. Myland and Keith B. Oldham, Journal of Electroanalytical
Chemistry, unpublished.
(156) "Diffusion-controlled current
densities close to a right-angled electrode edge", Keith B. Oldham,
Journal of Electroanalytical Chemistry, 420, 53-61 (1997).
(155) "The voltammetric response of a
conical electrode", Artjom V. Sokirko and Keith B. Oldham, Journal of
Electroanalytical Chemistry, 430, 15-24 (1997).
(154) "Diffusive analyte loss in
capillary electrophoresis caused by delay in field application", Christa
L. Colyer, Jan C. Myland and Keith B. Oldham, Journal of Chromatography A, 732,
335-344 (1996).
(153) "The three-dimensional simulation
of short-time diffusion-controlled voltammetry at the walls of a hollow
cube", Jan C. Myland and Keith B. Oldham, Journal of Electroanalytical
Chemistry, 405, 39-50 (1996).
(152) "Steady-state currents at
sphere-cap microelectrodes and electrodes of related geometry", L.C.
Roland Alfred and Keith B. Oldham, Journal of Physical Chemistry, 100,
2170-2177 (1996).
(151) "Emersion peaks in capillary
electrophoresis", Christa L. Colyer and Keith B. Oldham, Journal of Chromatography
A, 716, 3-15 (1995).
(150) "Tables of semiintegrals",
Keith B. Oldham, Journal of Electroanalytical Chemistry, 430, 1-14
(1997).
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